If you are using streaming mode (which is default)
master_slave_mode = on
# Activate master/slave mode
# (change requires restart)
You need to configure following to check replication status:
# - Streaming -
sr_check_period = 10
# Streaming replication check period
# Disabled (0) by default
sr_check_user = 'nobody'
# Streaming replication check user
# This is neccessary even if you disable streaming
# replication delay check by sr_check_period = 0
sr_check_password = ''
# Password for streaming replication check user
# Leaving it empty will make Pgpool-II to first look for the
# Password in pool_passwd file before using the empty password
sr_check_database = 'postgres'
# Database name for streaming replication check
delay_threshold = 10000000
# Threshold before not dispatching query to standby node
# Unit is in bytes
# Disabled (0) by default
Here is the documentation of this feauture:
https://www.pgpool.net/docs/latest/en/html/runtime-streaming-replication-check.html