Authenticode is only the type of signature.
Have you double clicked on the certificate that was used to create the signature. The Shell Extension for Windows Explorer might tell you whats wrong - e.g. Untrusted (root/issuer is not in Trusted Certificate Authorities Store), expired, revoked...
Digging deeper (CRL and OCSP):
Revocation checking is done besed of Certificate Revocation Lists (CRL) and Online Certificate Status Protocol (OCSP).
Here is a white paper for Windows.
Using .NET (C#)
X509Chain ch = new X509Chain();
ch.ChainPolicy.RevocationMode = X509RevocationMode.Online;
ch.Build (certificate);
Console.WriteLine ("Chain Information");
Console.WriteLine ("Chain revocation flag: {0}", ch.ChainPolicy.RevocationFlag);
Console.WriteLine ("Chain revocation mode: {0}", ch.ChainPolicy.RevocationMode);
Console.WriteLine ("Chain verification flag: {0}", ch.ChainPolicy.VerificationFlags);
Console.WriteLine ("Chain verification time: {0}", ch.ChainPolicy.VerificationTime);
Console.WriteLine ("Chain status length: {0}", ch.ChainStatus.Length);
Console.WriteLine ("Chain application policy count: {0}", ch.ChainPolicy.ApplicationPolicy.Count);
Console.WriteLine ("Chain certificate policy count: {0} {1}", ch.ChainPolicy.CertificatePolicy.Count, Environment.NewLine);
Source: https://learn.microsoft.com/en-us/dotnet/api/system.security.cryptography.x509certificates.x509chain.build?view=netframework-4.8
- DigiCert offers a tool which is is helpful