In general, there is no algorithm for converting a recursive form into an iterative one. This problem is undecidable. As an example, consider this recursive function definition, which defines the Collatz sequence:
f(1) = 0
f(2n) = 1 + f(n)
f(2n + 1) = 1 + f(6n + 4)
It's not known whether or not this is even a well-defined function or not. Were an algorithm to exist that could convert this into a closed-form, we could decide whether or not it was well-defined.
However, for many common cases, it is possible to convert a recursive definition into an iterative one. The excellent textbook Concrete Mathematics spends much of its pages showing how to do this. One common technique that works quite well when you have a guess of what the answer is is to use induction. As an example for your case, suppose that you believe that your recursive definition does indeed give 3^n - 1. To prove this, try proving that it holds true for the base cases, then show that this knowledge lets you generalize the solution upward. You didn't put a base case in your post, but I'm assuming that
f(0) = 0
f(1) = 2
Given this, let's see whether your hunch is correct. For the specific inputs of 0 and 1, you can verify by inspection that the function does compute 3^n - 1. For the inductive step, let's assume that for all n' < n that f(n) = 3^n - 1. Then we have that
f(n) = 2f(n - 1) + 3f(n - 2) + 4
= 2 * (3^{n-1} - 1) + 3 * (3^{n-2} - 1) + 4
= 2 * 3^{n-1} - 2 + 3^{n-1} - 3 + 4
= 3 * 3^{n-1} - 5 + 4
= 3^n - 1
So we have just proven that this recursive function does indeed produce 3^n - 1.