Bernstein's algorithm returns (one or more) components in EKNF, which lies between 3NF & BCNF.
Your claims of "that subrelation will therefore be in BCNF" are wrong. The FDs that hold in a component are all the ones in the closure of the original relation whose attributes are all in the component. So FDs could hold in a component that are not out of its superkeys. (Which by definition of BCNF is just another way of saying a component could be not in BCNF. Obviously--since we are told that the algorithm doesn't always give BCNF.)
Since your reasoning is unsound, finding a counterexample seems moot. But just about any presentation of BCNF gives an example non-BCNF 3NF relation, which it then decomposes to BCNF. You can join the non-BCNF 3NF relation with a projection on attributes of one of its CKs extended by a fresh non-prime attribute, and Bernstein's algorithm can decompose back to the 2 tables.
Chris Date's classic An Introduction to Database Systems has a non-BCNF 3NF schema R(S, J, T) with minimal/irreducible cover
{S, J} -> T
{T} -> J
CKs are {S, J} & {T, J}. Berstein gives component (S, J, T)--non-BCNF 3NF input R--in which both given FDs hold--plus redundant component (T, J).
For an example with an additional non-redundant component, extend the cover by {T} -> X
. CKs are the same. {S, J} -> T again gives (S, J, T)--non-BCNF--plus component (T, J, X).
So, could someone please give me an example of the 3NF synthesis algorithm yielding a non-BCNF decomposition and tell why it is so?
A better "So, [...]" would be, So, what is wrong with my reasoning? You would do well to examine the assumptions you made about what FDs could hold in a component. (That article happens to point out (with reference) that "A 3NF table that does not have multiple overlapping candidate keys is guaranteed to be in BCNF.")
There is no "why" in mathematics. We assume things ("assumptions", "axioms", "premises") & other things follow. We can ask for a proof of something, but the proof does not say "why" the something is so, it's a demonstration that it is so. "Why" might be used trying to ask for a proof or for steps that you got wrong in or are missing from whatever almost-proof you have in mind.
PS Such a ubiquitous non-BCNF 3NF relation is Today's Court Bookings in the Wikipedia article on BCNF as I write. But beware that that particular example has perhaps unintuitive FDs. Indeed beware that almost every relational model Wikipedia page--including that one--has errors & misconceptions. So do many, many textbooks, especially re normalization.