I don't see anything wrong with your regular expression syntax as it is quoted correctly so I assume there must be a bug in Guile, or the regexp library it uses, where \]
just isn't interpreted the correct way inside brackets. I found a workaround by using the octal code point values instead:
(string-match "[A-Za-z\\[\\0135]+" "Text [a,b]")
; ==> #("Text [a,b]" (0 . 4))
Your regular expression isn't very good. It matches any combination of those chars so "]/Te,3.xt[2"
also matches. If you are expecting a string like "Something [something, something]" I would rather have made /[A-Z][a-z0-9]+ [[a-z0-9]+,[a-z0-9]+]/ instead. eg.
(define pattern "[A-Z][a-z0-9]+ \\[[a-z0-9]+,[a-z0-9]+\\]")
(string-match pattern "Test [q,w]") ; ==> #("Test [q,w]" (0 . 10))
(string-match pattern "Be100 [sub,45]") ; ==> #("Be100 [sub,45]" (0 . 14))