You can use this regex which will match three characters where first and third are same using back reference, where as middle can be any,
(.).\1
Demo
Edit:
Above regex will only give you non-overlapping matches but as you want to get all matches that are even overlapping, you can use this positive look ahead based regex which doesn't consume the next two characters instead groups them in group2 so for your desired output, you can append characters from group1 and group2.
(.)(?=(.\1))
Demo with overlapping matches
Here is a Java code (I've never programmed in Ruby) demonstrating the code and the same logic you can write in your fav programming language.
String s = "b9fgh9f1;2w;111b2b35hw3w3ww55";
Pattern p = Pattern.compile("(.)(?=(.\\1))");
Matcher m = p.matcher(s);
while(m.find()) {
System.out.println(m.group(1) + m.group(2));
}
Prints all your intended matches,
111
b2b
w3w
3w3
w3w
Also, here is a Python code that may help if you know Python,
import re
s = 'b9fgh9f1;2w;111b2b35hw3w3ww55'
matches = re.findall(r'(.)(?=(.\1))',s)
for m in re.findall(r'(.)(?=(.\1))',s):
print(m[0]+m[1])
Prints all your expected matches,
111
b2b
w3w
3w3
w3w