See below for a proper self-contained working DocuSign envelope using multi-part form vs multipart/form-data -
DocuSign Support Case 04093516 is closed and a Jira ticket was filed for the erroneous mention of form-data in the documentation about sending envelopes via REST API.
Hard returns and spacing are critical. Also, recommend you update email addresses to your test Gmail account, notice the same account with + can be used.
If using Postman make sure you are using "RAW" not form-data, x-www-form-urlencoded or binary. See image below:

Link here as well - https://blog.grigsbyconsultingllc.com/wp-content/uploads/Screenshot-2018-04-18-07.26.26.png
You still need headers, specifically content-type and authentication type aka :
-H 'content-type: multipart/form-data; boundary=AAA' \
-H 'x-docusign-authentication; See Stack Overflow link How should the header X-DocuSign-Authentication be used for REST and SOAP?
--AAA
Content-Type: application/json
Content-Disposition: form-data
{
"emailBlurb": "Test for CEFTAF Lab 2 Custom Fields Recipient Fields Document Fields",
"emailSubject": "Test for Dev 201 Lab 2",
"status": "created",
"notification":{
"useAccountDefaults":"false",
"reminders":{
"reminderEnabled":"true",
"reminderDelay":"2",
"reminderFrequency":"2"
},
"expirations":{
"expireEnabled":"true",
"expireAfter":"15",
"expireWarn":"1"
}
},
"compositeTemplates": [{
"inlineTemplates": [{
"sequence": "1",
"customFields": {
"textCustomFields": [
{
"fieldId": "123",
"name": "MYCustomID",
"show": "false",
"required": "false",
"value": "myId012345"
}
],
"listCustomFields": [
{
"listItems": [
"elementValue1","elementValue2","elementValue3"
],
"fieldId": "1234",
"name": "myArrayListofItems",
"show": "false",
"required": "false",
"value": "3"
}
]
},
"documents": [{
"documentId": "1",
"name": "test1.txt",
"documentFields": [
{
"name": "Test1",
"value": "value for test1"
}
],
},
{
"documentId": "2",
"name": "test2.txt"
},
{
"documentId": "3",
"name": "test3.txt"
}
],
"recipients": {
"carbonCopies": [
{
"email": "dsproservedemosoapui+Testcc@gmail.com",
"name": "David Grigsby (see all document)",
"recipientId": "3",
"routingOrder": "3"
},
{
"email": "dsproservedemosoapui+Testcc1@gmail.com",
"name": "David Grigsby (see all)",
"recipientId": "4",
"routingOrder": "4"
}
],
"signers": [{
"recipientId": "1",
"customFields": [
"Recip 1 ID 1234"
],
"name": "David Grigsby (Sees all)",
"email": "dsproservedemosoapui+Test1@gmail.com",
"routingOrder": "1",
"tabs": {
"signHereTabs": [{
"anchorString": "Sign1",
"tabLabel": "Sign Here 1"
}]
}
},
{
"recipientId": "2",
"name": "David Grigsby (sees all )",
"email": "david.grigsby@yahoo.com",
"routingOrder": "2",
"tabs": {
"signHereTabs": [{
"anchorString": "Sign2",
"tabLabel": "Sign Here 2"
}]
}
}
]
}
}]
}]
}
--AAA
Content-Type: application/txt
Content-Disposition: file; filename="test1.txt"; documentid=1
Test Document 1
Sign1 Here _______________________________ Custom1 Approve:
Sign2 Here _______________________________ Custom2 Approve:
--AAA
Content-Type: application/txt
Content-Disposition: file; filename="test2.txt"; documentid=2
Test Document 2
Sign1 Here _______________________________
--AAA
Content-Type: application/txt
Content-Disposition: file; filename="test3.txt"; documentid=3
Test Document 3
No Tabs for anyone means visbile to all by default unless excluded
--AAA--
And the difference for a PDF is below, recommend using Base64
--AAA
Content-Type: application/pdf
Content-Disposition: file; filename="f4506t.pdf"; documentid=1
Content-Transfer-Encoding: base64
JVBERi0xLjcNJeLjz9MNCjMwMSAwIG9iag08PC9MaW5lYXJpemVkIDEvTCA3NDAzMi9PIDMwMy9F
IDMzNjI2L04gMi9UIDczNjM4L0ggWyA2MzAgMjk2XT4+DWVuZG9iag0gICAgICAgICAgICAgICAg
.... pdf body bulk removed ......
o4IlmH0CxPYUYWBiYGBUB5PVDADOVQiaCmVuZHN0cmVhbQplbmRvYmoKc3RhcnR4cmVmCjg1MDUz
CiUlRU9GCg==
--AAA--
Image of Note from DocuSign Case:
