What is wrong?
I was able to reproduce what you've described here. I've ended up on metainformation command, specifically the SQLPrimaryKeys ODBC function call. I have used SQL Server Native Client 11.0 driver connected to Microsoft SQL Server Express 12.0.2000.8, local database server instance.
When I tried to execute the following SQL command (with TEST_2.0 database created) through a TFDQuery component instance with default settings (linked connection object was left with empty database connection parameter) in Delphi Tokyo application:
SELECT * FROM [TEST_2.0].INFORMATION_SCHEMA.TABLES
I got this exception raised when the SQLPrimaryKeys function was called with the CatalogName parameter set to TEST_2.0 (from within the metainformation statement method Execute):
[FireDAC][Phys][ODBC][Microsoft][SQL Server Native Client 11.0][SQL
Server]Could not find server 'TEST_2' in sys.servers. Verify that the
correct server name was specified. If necessary, execute the stored
procedure sp_addlinkedserver to add the server to sys.servers.'.
My next attempt was naturally modifying that CatalogName parameter value to [TEST_2.0] whilst debugging, but even that failed with similar reason (just failed for the name [TEST_2), so for me it seems that the SQLPrimaryKeys ODBC function implementation with the driver I've used cannot properly handle dotted CatalogName parameter values (it seems to ignore everything after dot).
What can I do?
The only solution seems to be just fixing ODBC drivers. Workaround I would suggest is not using dots in database names (as discussed e.g. in this thread). Another might be preventing FireDAC from getting dataset object metadata (by excluding fiMeta option from the Items option set). That will bring you the responsability of supplying dataset object metadata by yourself (at this time only primary key definition).