Severe misunderstanding: Nothing gets the stored PIN from the card. Using the VERIFY command you can only supply a comparison value and find out, whether it is correct - if it is not, the retry counter will decrease and the PIN may block. There is the standard command CHANGE REFERENCE DATA, see ISO 7816-4, but standard commands have CLA=00 while you currently try CLA=80 (first byte of the command).
6D00 can also be found there and since it means "wrong INS code" the whole command may be wrong. (A PIN consisting of non-printable bytes is also somewhat untypical.)
Without knowing, which card you have and which specification it complies to, you will not make significant progress.
While WINSCARD may be your friend to get the command transported, it will not help in the respect of finding the correct bytes.