First of all figure out the LSB (least significant bit) of the ADC.
Example: The ADC uses a vref of 1.2V and has 8bit => LSB=1.2V/(2^8-1)=4.7mV
A typical temperature sensor using a bipolar junction has about -2mV/K. The example ADC with LSB=4.7mV will respond with a change of 1LSB per 2.35K temperature decrease.
A change of 1LSB/second means you have a change of -2.35K/per second.
If this isn't accurate enough for your application you can use an ADC with more bits or stack several diodes acting as temperature sensors.
If you use something else than a bipolar junction the sensitivity of the temperature sensor can be different. Just check the spec of the sensor and the ADC (and it's reference to calculate the LSB)
Parameters you need:
- Reference voltage of the ADC
- Number of bits of the ADC (to calculate LSB)
- Temperature coefficient of the sensor