If I understand your question correctly (I'm making a big assumption here) - you want to select an attribute from the root (or 'enclosing') tag, named 'url'?
You can make use of XPath queries here. Consider the following XML:
<?xml version="1.0" encoding="utf-8"?>
<root url='google.com'>
<inner />
</root>
You could use the following code to retrieve 'google.com':
String query = "/root[1]/@url";
XmlDocument doc = new XmlDocument();
doc.Load(sourceURLX);
String value = doc.SelectSingleNode(query).InnerText;
Further information about XPath syntax can be found here.
Edit: As you stated in your comment, you are working with the following XML:
<item>
<description>
</description>
<enclosure url="blablabla.com/img.jpg" />
</item>
Therefore, you can retrieve the url using the following XPath query:
/item[1]/enclosure[1]/@url