If you just want to learn the Drools language you should use Eclipse/Idea and check out the code examples Drools releases deliver. The Drools documentation describes few of them and walks you through them. Once you can run them in your IDE start changing parts from here and there to see how the run results change.
The workbench offers a lot of tools for authoring rules in different formats: with plain DRL that is the Drools language and with different guided editors that hide the actual Drools syntax and give you a more visual editor for rule authoring.
The workbench also gives you tools for releasing and managing released rule projects, but it is hard to learn the actual language since there is no good way to run the rules in the workbench. You need to either use Test Scenarios to run the rules or build a kjar out of your project and then use it in an application that you would have to write yourself.
Best to start with an IDE and just use the premade examples.