You can, with the ORDER BY
clause be specific with the order returned so perhaps for your needs you can try:
select * from `products` where `id_category` = :id_category order by `id`=5 desc;
As an example of how this changes the ordering consider the following
mysql> select * from accounts;
+----+-----------+----------+----------+
| id | sponsorID | open | close |
+----+-----------+----------+----------+
| 1 | 23 | 6:00 AM | 10:30 PM |
| 2 | 23 | 6:00 AM | 8:30 PM |
| 3 | 21 | 11:00 AM | 5:30 PM |
| 4 | 23 | 7:00 AM | 2:30 PM |
| 5 | 24 | 9:00 AM | 11:30 PM |
| 6 | 25 | 6:00 AM | 9:30 PM |
| 7 | 99 | 6:00 AM | 9:30 PM |
+----+-----------+----------+----------+
mysql> select * from accounts order by id=5 desc;
+----+-----------+----------+----------+
| id | sponsorID | open | close |
+----+-----------+----------+----------+
| 5 | 24 | 9:00 AM | 11:30 PM |
| 1 | 23 | 6:00 AM | 10:30 PM |
| 2 | 23 | 6:00 AM | 8:30 PM |
| 3 | 21 | 11:00 AM | 5:30 PM |
| 4 | 23 | 7:00 AM | 2:30 PM |
| 6 | 25 | 6:00 AM | 9:30 PM |
| 7 | 99 | 6:00 AM | 9:30 PM |
+----+-----------+----------+----------+
You can specify more than one explicit term in the order by or mix the ordering of subsequent columns
mysql> select * from accounts order by id=5 desc, id desc;
+----+-----------+----------+----------+
| id | sponsorID | open | close |
+----+-----------+----------+----------+
| 5 | 24 | 9:00 AM | 11:30 PM |
| 7 | 99 | 6:00 AM | 9:30 PM |
| 6 | 25 | 6:00 AM | 9:30 PM |
| 4 | 23 | 7:00 AM | 2:30 PM |
| 3 | 21 | 11:00 AM | 5:30 PM |
| 2 | 23 | 6:00 AM | 8:30 PM |
| 1 | 23 | 6:00 AM | 10:30 PM |
+----+-----------+----------+----------+
or
mysql> select * from accounts order by id=5 desc, id=1 desc, id desc;
+----+-----------+----------+----------+
| id | sponsorID | open | close |
+----+-----------+----------+----------+
| 5 | 24 | 9:00 AM | 11:30 PM |
| 1 | 23 | 6:00 AM | 10:30 PM |
| 7 | 99 | 6:00 AM | 9:30 PM |
| 6 | 25 | 6:00 AM | 9:30 PM |
| 4 | 23 | 7:00 AM | 2:30 PM |
| 3 | 21 | 11:00 AM | 5:30 PM |
| 2 | 23 | 6:00 AM | 8:30 PM |
+----+-----------+----------+----------+