You can refer to sample on detecting non-occurrences with patterns.
However, since you want to check whether REQ event came before PO event you might need to use in-memory event tables to cater your requirement. Refer to the following sample on achieving the same using in-memory tables;
@Import('REQStream:1.0.0')
define stream REQ (ITEM_ID int, QUANTITY int, CREATED_BY string);
@Import('POStream:1.0.0')
define stream PO (ITEM_ID int, QUANTITY int, CREATED_BY string);
@Export('ALERTStream:1.0.0')
define stream ALERT (ITEM_ID int, ALERT string);
define table REQ_TABLE (ITEM_ID int, QUANTITY int, CREATED_BY string);
define trigger DAILY_TRIGGER at every 1 day;
from REQ
insert into REQ_TABLE;
-- check whether request exists before the purchase
from PO[not((REQ_TABLE.ITEM_ID == ITEM_ID and REQ_TABLE.QUANTITY == QUANTITY and REQ_TABLE.CREATED_BY == CREATED_BY) in REQ_TABLE)]
select ITEM_ID, 'No REQ created before' as ALERT
insert into ALERT;
-- purge reauests table daily
from DAILY_TRIGGER join REQ_TABLE
select REQ_TABLE.ITEM_ID, REQ_TABLE.QUANTITY, REQ_TABLE.CREATED_BY
insert into PURGE_STREAM;
-- if there's no matching purchase order came up for previous day
from PURGE_STREAM
select ITEM_ID, 'No purchase order came up for a day' as ALERT
insert into ALERT;
from PO
insert into DEL_STREAM;
from PURGE_STREAM
insert into DEL_STREAM;
-- delete corresponding request from table
from DEL_STREAM
delete REQ_TABLE
on REQ_TABLE.ITEM_ID == ITEM_ID and REQ_TABLE.QUANTITY == QUANTITY and REQ_TABLE.CREATED_BY == CREATED_BY;