You can use a counter that is incremented one for each scan cycle and then a case structure to control which commands are active at each scan:
VAR
i: INT;
END_VAR
(* Main code to be executed at each scan cycle *)
(* The commands could be either actions to MAIN() or separate POUs *)
i := i + 1;
IF i > 10 THEN
i := 1;
END_IF;
CASE i OF
1: (* Call one command *)
Command1();
2, 4, 6, 8, 10: (* These scans all call the same command *)
Command2();
5: (* Call 3 different commands *)
Command3();
Command4();
Command5();
(* Scans 3, 7 and 9 do nothing *)
END_CASE;