No, Android does not send any notification like "hey, there is some app that has just been activated over HCE". Thus, you can't get such an event in your app. And specifically, it's not possibly to monitor if any existing HCE app (that's not under your control) on your device has been activated through HCE.
What you can do is to create your own HCE service (registered for your specific application AIDs). This HCE service could then launch an activity if it receives a transaction (also see How can I send message from HostApduService to an activity?):
public class MyHostApduService extends HostApduService {
@Override
public byte[] processCommandApdu(byte[] apdu, Bundle extras) {
if ((apdu[1] == (byte)0xA4) && (apdu[2] == (byte)0x04)) {
// SELECT by AID
Intent intent = new Intent(this, MyActivity.class);
intent.addFlags(Intent.FLAG_ACTIVITY_NEW_TASK);
startActivity(intent);
return new byte[]{ (byte)0x90, (byte)0x00 }
} else {
return new byte[]{ (byte)0x6D, (byte)0x00 }
}
}
}