Let's start with some introductions before answering the questions
Using the REPL you can understand a bit more what you are doing
scala> List("1", "2", "3", "33").map(x => x(0).toInt)
res1: List[Int] = List(49, 50, 51, 51)
The map function is used to transform every element, so x inside the map will be "1" the first time, "2" the second, and so on.
When you are using x(0) you are accessing the first character in the String.
scala> "Hello"(0)
res2: Char = H
As you see the type after you have mapped your strings is a List of Int. And you can compare that with an Int, but it will never be equals.
scala> List(1, 2, 3) == 5
res0: Boolean = false
This is very much like in Java when you try
"Hello".equals(new Integer(1));
If you want to know more about the reasons behind the equality problem you can check out Why has Scala no type-safe equals method?
Last but not least, you get an error when using less than because there is no less than in the List class.
Extra:
If you want to know if the second element in the list is smaller than 2 you can do
scala> val data = List("1", "10", "20")
data: List[String] = List(1, 10, 20)
scala> 5 < data(1).toInt
res2: Boolean = true
Although it is a bit strange, maybe you should transform the list of string is something a bit more typed like a case class and then do your business logic with a more clear data model.