As other answers have already pointed out, you can only initialise a character array with a string literal, you cannot assign a string literal to a character array. However, structs (even those that contain character arrays) are another kettle of fish.
I would not recommend doing this in an actual program, but this demonstrates that although arrays types cannot be assigned to, structs containing array types can be.
typedef struct
{
char value[100];
} string;
int main()
{
string a = {"hello"};
a = (string){"another string!"}; // overwrite value with a new string
puts(a.value);
string b = {"a NEW string"};
b = a; // override with the value of another "string" struct
puts(b.value); // prints "another string!" again
}
So, in your original example, the following code should compile fine:
typedef struct{
char a[6];
} point;
int main()
{
point p;
// note that only 5 characters + 1 for '\0' will fit in a char[6] array.
p = (point){"onetw"};
}