In addition to models, have you looked at Config/database.php?
Models with joins and associations are supported.
Is this a read-only app, or will it be maintaining tables. If you are read-only, you can get running pretty quick by doing basic model stuff without worrying about joins and associations.
To leverage Cake's multi database capabilities, make sure you understand the model.php variable $useDbConfig and how it relates to Config/database.php
Often, within the model class in the model.php file where model is the name of the model for a given table,
public $useDbConfig = "PostgressOnAix";
Also, probably doesn't apply for you, but in Cakephp you can do this;
$this->loadModel("TableStoredTwoPlaces");
$this->TableStoredTwoPlaces->useDbConfig = "PostgresOnAix";
or even;
$modelName = "TableStoredTwoPlaces";
$this->loadModel($modelName);
$this->$modelName->useDbConfig = "PostgresOnAix";
The value of the model setting of useDbConfig maps to a variable defining and array in Config/database.php within the class DATABASE_CONFIG