As far as I understand it both Clang and GCC are shipped with the Android and iOS crossplatform SDKs/tools for Visual Studio 2015.
From what I've seen it only allows me to choose those while having one of those crossplatform projects.
Using the template project for a GLES C++ application you get the following options:

While for a Windows C++ application you get the dialog below where you can see that Windows target platform is grayed out and read-only, meaning you probably have a set of toolkits for each target platform, but you simply cannot change it, at least for now.

Have no idea how you turn a normal VS project into crossplatform though, and it's likely that you can only target Android or iOS out of the box using 3rd party compilers.
It may be possible, though, to install Clang as another toolkit in the same way the XP toolkits are. So perhaps it's just a matter of someone fiddling with it and making it available as it is already installed.
Caveat: This answer is pre-VS2015 update 1 which didn't have the "Clang with Microsoft CodeGen" option.