Modern compilers are capable of producing such a warning...in gcc, it's turned on with -Wmissing-field-initializers (which warns about initializers that exist but do not initialize all members, but not about structs with no initializer expression; these can at least sometimes be caught by turning on -Wuninitialized, which will warn you if it sees you reading a potentially uninitialized value, at least if you read it in the same function the variable was declared in).
If your very old compiler happens to supply such a warning, you could of course just turn it on, but that seems unlikely from your description.
Your best option, I think, if you want to do an exhaustive search for them, would be to see whether you can get the code to compile with some version of gcc -- it wouldn't have to compile well enough to actually run on your target platform in order to get the warnings. I can't guarantee that it will be able to compile your pre-ANSI C code, particularly if it widely uses compiler-specific extensions, but I can at least say that support for the legacy K&R syntax is still present in the modern C standard, so I wouldn't be surprised if your code compiles better than you might think.
If that works, then to consistently produce the warnings in your IDE, you could modify the build script so that it both compiles and links the code with the real compiler you're targeting, and also compiles it (but not necessarily links it) with gcc, just to generate additional warnings that can be picked up and displayed by the IDE.
The other option would be to see if you can find a compatible static analyzer that can perform such a check; I work on a tool called EnSoft Atlas that builds a data-flow graph which, together with a simple script, could be used to enforce initialization more thoroughly than the gcc warnings allow, by checking whether flow of uninitialized values to fields of structs occurs.
However, our support for C is still in beta. Atlas requires that Eclipse CDT (or JDT for Java) be able to parse your code, and the current C beta only fully supports modern strongly-typed struct initializers (i.e. struct foo f = (struct foo) {...}
has fully connected data-flow, but support for the older initializer list syntax struct foo f = {...}
was not implemented in our first pass), so I'm not sure it would be able to meet your needs at this time.