What you are trying to do is not allowed, for good reasons. First of all when you try to save a file from a web application on someone else's computer you have no idea whether the folder in which you try to save the file exists and whether the user has access to this folder. Also the webapplication does not know if the computer that is being used is a Windows computer, Mac, Linux or maybe a telephone, for which all filesystems work different. Second, and more importantly, it is a huge risk if a website was able to save a file to any folder, for example your start-up folder. A malicious website would be able to install viruses/keylogger/etc. on your computer without you knowing it.
So if you want to save an Excel file to a specific folder you must make a console application or a Windows application.