From the documentation, it seems like we should be able to query individual map elements:
http://www.datastax.com/documentation/cql/3.1/cql/cql_using/use_map_t.html
Each element of the map is internally stored as one Cassandra column that you can modify, replace, delete, and query.
The examples show updating individual elements, but similar syntax doesn't seem to work for select statements. Is there a way to select only one key-value for a map column?