It is possible, to a certain degree, to get dynamic recipient.
In the SMTP appender the replacements for To, CC, From etc is done during configuration. Not ideal (would be best if it were to calculate the values at every send) but still workable.
Re-configuring the logging is not free but is doable programatically. You can set your To field as such :
<to type="log4net.Util.PatternString" value="SomeAccountThatReceivesAll@yourCorp.com%property{MailRecipient}" />
then in your code you can set a comma separated list of recipient like this :
log4net.GlobalContext.Properties["MailRecipient"] = "SomeOtherAccount@yourCorp.com,YourCorpSupportForThisApp@yourCorp.com";
the important bit is that you force a re-configuration AFTER you set these values. The exact syntax will depend on your config strategy, we use a central config file for all the logging so in C# it would look like this :
log4net.Config.XmlConfigurator.ConfigureAndWatch("PathToYourCentralFile.xml");
and voila ! Dynamic recipient without any custom appenders !
Personally I would prefer the custom appender, less hackish as it does not require constant re-configuring if you need to change them often. But if you only need the 10 minute fix and the config for recipient does not change once started then I found this to be good enough.