Is there a way to login my hotmail account and send mails with a Python program?
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You can try using their SMTP server:
- User name: Your Windows Live ID, for example yourname@hotmail.com
- Password: The password you usually use to sign in to Hotmail or Windows Live
- SMTP server: smtp.live.com (Port 25) {Note: If port 25 has been blocked in your network or by your ISP, you can set SMTP port to 587 with TLS or SSL Encryption depending on the client in use}
- Authentication required? Yes (this matches your POP username and password)
- TLS/SSL required? Yes

Nikola Smiljanić
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