Have you tried setting the style described here:
http://msdn.microsoft.com/en-us/library/ee957369.aspx
under "Binding to Content Size"?
Binding to Content Size
As described in ScatterView Overview, by default a ScatterViewItem
does not necessarily expand or contract to the size of its content.
You can explicitly set the Height and Width properties of a
ScatterViewItem, but sometimes your content may be a control of an
unknown size, or your content might have variable size.
In cases like this, we recommend that you bind the dimensions of the
ScatterViewItem to the dimensions of the content. To do so, you need
to define a Style object (usually within the Resources section of your
main application window). The following code example shows a Style
object declaration that you can apply to a ScatterViewItem control to
cause it to bind to the dimensions of its content.
<Style x:Key="ScatterViewItemStyle" TargetType="{x:Type s:ScatterViewItem}">
<Setter Property="MinWidth" Value="{Binding Path=Content.MinWidth, RelativeSource={RelativeSource Self}, Mode=OneWay}"/>
<Setter Property="MinHeight" Value="{Binding Path=Content.MinHeight, RelativeSource={RelativeSource Self}, Mode=OneWay}"/>
<Setter Property="MaxWidth" Value="{Binding Path=Content.MaxWidth, RelativeSource={RelativeSource Self}, Mode=OneWay}"/>
<Setter Property="MaxHeight" Value="{Binding Path=Content.MaxHeight, RelativeSource={RelativeSource Self}, Mode=OneWay}"/>
<Setter Property="Width" Value="{Binding Path=Content.Width, RelativeSource={RelativeSource Self}, Mode=TwoWay}"/>
<Setter Property="Height" Value="{Binding Path=Content.Height, RelativeSource={RelativeSource Self}, Mode=TwoWay}"/>
<Setter Property="Template">
<Setter.Value>
<ControlTemplate TargetType="{x:Type s:ScatterViewItem}">
<ContentPresenter />
</ControlTemplate>
</Setter.Value>
</Setter> </Style>
When you want to create a ScatterViewItem that uses the dimensions of
its content, apply the style to the ScatterViewItem as shown in the
following code example.
<s:ScatterViewItem Style="{StaticResource ScatterViewItemStyle}">
<Rectangle Height="250" Width="250" Fill="Red" /> </s:ScatterViewItem>