println
is defined in the object scala.Predef
. The members of which is always in scope, there is no way you can add to that, but as the question linked to by senia says you can achieve sort of the same by defining a method in a package object which will then be available inside code in that package.
Another solution that some libraries uses is to provide an Imports object with aliases and shortcuts just like Predef, but that you have to explicitly import with a wildcard. For example nscala-time does this:
import com.github.nscala_time.time.Implicits._