My solution is to use the latest Eclipse version (Mars.1 Release (4.5.1)) which seems to work properly.
The only operations to do for the XML files is to add the button to the toolbar like this:
- Use or open the
Java EE
Perspective
- Open any xml file in a project (e.g. blueprint.xml)
- Go to menu:
Windows
-> Perspective
-> Customize Perspective
- In the opened dialog window, choose the tab
Action Set Availability
- In the column
Available action sets:
check the Editor Presentation
- Press OK button to close the popup window.
Here is the windows dialog after checking the right option:

The three buttons appears now in the toolbar, not greyed-out.
UPDATE: However I found that if I open a pom.xml file the button is still greyed-out, but if I open another plain xml (blueprint.xml or one from a test) it is not.
It seems there is a bug with the pom viewer. As a workaround, I created a key shortcut (e.g AltGr + W) and it works in the pom.xml as well with the shortcut.