Many older computers (such as the UNIVAC 2200 and PDP-15) had words that were multiples of 6 bits (18 and 36 bits being most common).
Octal was used a lot for these systems (an octal digit is three bits, so it fits nicely).
Modern systems have words which are multiples of 8 bits (8, 16, 32 and 64 being common).
Hex is used a lot for these systems (a hex digit is four bits, so it fits nicely).
How, when and why did this happen?
Was the octal->hex change causal or a consequence?
I have already read.