Doing this sort of this is not as simple as you think. Controlling the data above the IP layer is relatively easy using normal socket APIs, but controlling data below is a bit more involved. Most operating systems make changing lower-level protocol information difficult since the kernel itself manages network connections and doesn't want you messing things up. Beyond that, there are other platform differences, network controls, etc that can play havoc on you.
You should look into some of the libraries that are out there to do this. Some examples:
If your goal is to spoof packets, you should read up on network-based spoofing mitigation techniques too (for example egress filtering to prevent spoofed packets from exiting a network).