Your config file might have a connectionStrings section like this:
<connectionStrings>
<add name="ConnectionNumberOne"
connectionString="Data Source=ds;Initial Catalog=DB;Integrated Security=True"
providerName="System.Data.SqlClient" />
<add name="ConnectionNumberTwo"
connectionString="Data Source=ds2;Initial Catalog=DB2;Integrated Security=True"
providerName="System.Data.SqlClient" />
</connectionStrings>
You can read the connection string thusly:
var connectionOne = System.Configuration.ConfigurationManager.ConnectionStrings["ConnectionNumberOne"];
var connectionTwo = System.Configuration.ConfigurationManager.ConnectionStrings["ConnectionNumberTwo"];
And you can save the connection string as well:
Configuration config = ConfigurationManager.OpenExeConfiguration(ConfigurationUserLevel.None);
config.ConnectionStrings.ConnectionStrings["ConnectionNumberOne"].ConnectionString = //CONCATINATE YOUR FIELDS TOGETHER HERE
config.Save(ConfigurationSaveMode.Modified, true);
ConfigurationManager.RefreshSection("connectionStrings");