If you mean Nvidia then it's clearly RISC as its most GPUs don't even have integer division and modulo operations in hardware, only shifts, bitwise operations and 3 arithmetic operations (addition, subtraction, multiplication) are used to implement those 2. I can't find example but this question (modular arithmetic on the gpu) shows that mod uses
procedure which implements some sophisticated algorithm (about 50 instructions or even more)
Even NVVM (Nvidia virtual machine) language called PTX uses more operations some of which are "baked" into a bunch of simpler operations anyway after conversion to one of native languages (there are different versions of such languages because of nature of GPUs and their generations/families but those are just called SASS altogether).
You can see here all the available operations along with description on each which are yet very short and not very clear (especially if you don't have background in machine level programming like knowing that "scaled" means 1 left shifted to operand just as in x86's "FSCALE" or "Scale factor" etc.):
https://docs.nvidia.com/cuda/cuda-binary-utilities/index.html#instruction-set-ref
If you mean AMDGPU then there is a lot of instructions and it's not so clear because some sources tell that they switched from VLIW to something just when Southern Islands GPUs were released.