For start, please note that "heap" property requires that subtrees rooted at non-leaf nodes should also maintain the heap property because they are also heaps. For min-heap, the "heap" property is that root value should be less than values at the children.
If any non-leaf node of a min-heap holds the maximum item, then the heap property of the subtree whose root is the current non-leaf node is violated because children values of this subtree is less than the root value. To maintain the heap property, the root value has to be floated down to one of the children.
In order to not violate the "heap" property, the floating down of the "maximum" item will continue until the node holding the maximum value has no more children. Thus, the "maximum" item will always be at a node that has no children (i.e. leaf node).