Are the values of Row 1 and Row 5 constant, or will the row numbers you are calculating on always be 1 and 5?
You could use custom code to store the values in variables and then perform the calculation using those.
Create a function which takes both Col1 value and the calculated value of Col2. It will then assign Row1 to var1 and Row5 to var2. It will then return the value of Col2 for display as the Total value.
Make sense? Let me know if you need some help with the function...
EDIT
SSRS:
Col 1 | Col 2 | Col 2 Expression
England | 201 | =Code.SetOneFive(Count(Fields!Country.Value))
Ireland | 451 | =Code.SetOneFive(Count(Fields!Country.Value))
Scotland | 215 | =Code.SetOneFive(Count(Fields!Country.Value))
Wales | 487 | =Code.SetOneFive(Count(Fields!Country.Value))
Zenovia | 2145 | =Code.SetOneFive(Count(Fields!Country.Value))
Code:
Public Shared Dim i as Integer = 1
Public Shared Dim rowOne as Integer
Public Shared Dim rowFive as Integer
Public Function SetOneFive (byval _OneFive As Integer) as Integer
If i = 1 then
rowOne = _OneFive
Else If i = 5 then
rowFive = _Onefive
End If
i = i + 1
End Function
Public Function GetRowOne () As Integer
GetRowOne = RowOne
End Function
Public Function GetRowFive () As Integer
GetRowFive = RowFive
End Function
For every iteration of the code, i is increased by 1. This is checked every iteration for a value of 1 or 5.
In your total column you can then use:
=Code.GetRowFive() / Code.GetRowOne()
Note: I haven't tested this so there could be some typos or syntactical errors, but you get the general idea.
Depending on how you use this you may want to consider not declaring the variables as 'shared':
SSRS code variable resetting on new page