To measure the RF clock (26 MHz) with an oscilloscope, you need to:
1 - output the clock from the radio module to the core, e.g. through the signal GDO1 (internal signal between the RF SoC and the core). To do that, adjust the corresponding value in the RF config table, see 25.3.5 of the CC430 family user guide. To use GDO1, put 0x30 (RFCLK/1) in IOCFG1. See Table 25-21 if you need other dividers than 1 (depending on the limitations of your measuring equipment).
2 - map the radio module's signal GDO1 to a free IO pin.
PMAPKEYID = PMAPKEY; // Get write-access to port mapping regs
P2MAP6 = PM_RFGDO1; // Map radio GDO1 to output pin 2.6.
PMAPCTL |= PMAPRECFG; // Allow for future port map configurations.
PMAPPWD = 0x00; // Lock Port mapping
Set also the SEL and the DIR bits for the IO pin you are using.
3 - an oscilloscope (or frequency counter) that can measure 26 MHz accurately enough for your needs.
Note: measuring MCLK might not be accurate enough, its generation going through other disturbing stuff such as FLL...