From Intel's Architectures Software Developer's Manual, Volume 2C Appendix A (Opcode Map):
Table A-1. Superscripts Utilized in Opcode Tables
...
o64 Instruction is only available when in 64-bit mode
...
Searching the tables, the following instructions appear with that superscript:
- REX prefixes (not really an instruction but still)
- MOVSXD
- SYSCALL, SYSRET
- SWAPGS
A few additional instructions which are variants of existing ones are listed in section 5.16 (64-BIT MODE INSTRUCTIONS):
- CDQE Convert doubleword to quadword
- CMPSQ Compare string operands
- CMPXCHG16B Compare RDX:RAX with m128
- LODSQ Load qword at address (R)SI into RAX
- MOVSQ Move qword from address (R)SI to (R)DI
- MOVZX (64-bits) Move doubleword to quadword, zero-extension
- STOSQ Store RAX at address RDI