In addition to Jack's practical advice about p-values, the functions are well defined (if not practical) so I'll give the finite-precision mathematical reason this doesn't work.
.Machine$double.eps
is 2.220446e-16
and that is the smallest number that you can add to 1 and get something different. So differencing from 1, that is the smallest value you get.
> pf(80:90,1,200)
[1] 1 1 1 1 1 1 1 1 1 1 1
> sprintf("%.17f",pf(80:90,1,200))
[1] "0.99999999999999978" "0.99999999999999978" "0.99999999999999989"
[4] "0.99999999999999989" "1.00000000000000000" "1.00000000000000000"
[7] "1.00000000000000000" "1.00000000000000000" "1.00000000000000000"
[10] "1.00000000000000000" "1.00000000000000000"
> sprintf("%a", pf(80:90,1,200))
[1] "0x1.ffffffffffffep-1" "0x1.ffffffffffffep-1" "0x1.fffffffffffffp-1"
[4] "0x1.fffffffffffffp-1" "0x1p+0" "0x1p+0"
[7] "0x1p+0" "0x1p+0" "0x1p+0"
[10] "0x1p+0" "0x1p+0"
However you can use the approximation $1-p = -\ln(p)$ and the fact that you can get the log of the p-values more precisely
> -pf(80:90,1,200,log.p=TRUE)
[1] 2.540347e-16 1.770938e-16 1.236211e-16 8.640846e-17 6.047690e-17
[6] 4.238264e-17 2.974043e-17 2.089598e-17 1.470045e-17 1.035491e-17
[11] 7.303070e-18