There's really only two possibilities. One, your path is incorrect. Try this:
C:\Windows\Microsoft.NET>path
PATH=C:\Program Files\Common Files\Microsoft Shared\Microsoft Online Services;C:\Program Files (x86)\Common Files\Micros
oft Shared\Microsoft Online Services;c:\Program Files (x86)\AMD APP\bin\x86_64;c:\Program Files (x86)\AMD APP\bin\x86;C:
\oraclexe\app\oracle\product\11.2.0\server\bin;C:\Windows\system32;C:\Windows;C:\Windows\System32\Wbem;C:\Windows\System
32\WindowsPowerShell\v1.0\;C:\Program Files (x86)\QuickTime\QTSystem\;c:\Program Files (x86)\Microsoft SQL Server\100\To
ols\Binn\;c:\Program Files\Microsoft SQL Server\100\Tools\Binn\;c:\Program Files\Microsoft SQL Server\100\DTS\Binn\;C:\P
rogram Files (x86)\Java\jre6\bin;C:\Program Files (x86)\Graphviz 2.28\bin;C:\Program Files (x86)\1E\SMSNomad\;C:\Program
Files (x86)\Git\cmd;C:\Program Files (x86)\Git\bin;C:\Program Files (x86)\IronRuby 1.1\bin;C:\Program Files\Microsoft\W
eb Platform Installer\;C:\Program Files (x86)\Microsoft ASP.NET\ASP.NET Web Pages\v1.0\;C:\Program Files\Microsoft SQL S
erver\110\Tools\Binn\;C:\Program Files (x86)\Microsoft SDKs\TypeScript\0.8.0.0\
C:\Windows\Microsoft.NET>csc
'csc' is not recognized as an internal or external command,
operable program or batch file.
C:\Windows\Microsoft.NET>set path=%path%;C:\Windows\Microsoft.NET\Framework64\v4.0.30319
C:\Windows\Microsoft.NET>csc
Microsoft (R) Visual C# Compiler version 4.0.30319.17929
for Microsoft (R) .NET Framework 4.5
Copyright (C) Microsoft Corporation. All rights reserved.
warning CS2008: No source files specified
error CS1562: Outputs without source must have the /out option specified
C:\Windows\Microsoft.NET>
If that isn't working, then verify csc.exe is indeed in the correct location:
C:\Windows\Microsoft.NET>dir C:\Windows\Microsoft.NET\Framework64\v4.0.30319\csc.exe /b
csc.exe
If it isn't found, try doing:
C:\Windows\Microsoft.NET>dir csc.exe /s /b
C:\Windows\Microsoft.NET\Framework\v1.1.4322\csc.exe
C:\Windows\Microsoft.NET\Framework\v2.0.50727\csc.exe
C:\Windows\Microsoft.NET\Framework\v3.5\csc.exe
C:\Windows\Microsoft.NET\Framework\v4.0.30319\csc.exe
C:\Windows\Microsoft.NET\Framework64\v2.0.50727\csc.exe
C:\Windows\Microsoft.NET\Framework64\v3.5\csc.exe
C:\Windows\Microsoft.NET\Framework64\v4.0.30319\csc.exe
To see if it's in a different directory. Perhaps you have another version of the framework installed, or do not have a 64bit OS.