I'm sure you'll get a more complete answer later as I'm not sure how to write it recursively like your example, but maybe this variation would work for you:
scala> val pairs = List((1, "a"), (2, "b"), (3, "c"))
pairs: List[(Int, String)] = List((1,a), (2,b), (3,c))
scala> val n = 2
n: Int = 2
scala> pairs find {e => e._1 == n}
res0: Option[(Int, String)] = Some((2,b))
OK, next attempt at direct translation. How about this?
scala> def findPair[A, B](n: A, p: List[Tuple2[A, B]]): Option[Tuple2[A, B]] = p match {
| case Nil => None
| case head::rest if head._1 == n => Some(head)
| case _::rest => findPair(n, rest)
| }
findPair: [A, B](n: A, p: List[(A, B)])Option[(A, B)]