I see that people have had issues in the past with Heroku and SSL and matching .pem certs (like this: Heroku SSL error: key doesn't match PEM certificate).
However, our site has had ssl running fine, until it expired. We renewed with GoDaddy and have been following the instructions here: http://blog.matthodan.com/how-to-setup-heroku-hostname-ssl-with-godaddy
Now the weird thing is is that we're continually getting this read out- "Pem is invalid / Key doesn't match the PEM certificate"