Wampserver has a problem when loading php_pdo_pgsql and php_pgsql modules. After searching on several forums the solution is to download from http://www.bmedon.net/download.html both .dll files and overwrite the existing ones.
The problem is that it didn't work! I checked all php.ini files. I followed http://diego-loquese.blogspot.com/2010/12/conectar-wampserver-con-postgresql.html instructions (which is a summary of all the forums I found).
I am using WampServer 2.2 for Windows x64 with PHP 5.4.3