A dictionary will work, but .NET has associative arrays built in. One instance is the NameValueCollection class (System.Collections.Specialized.NameValueCollection).
A slight advantage over dictionary is that if you attempt to read a non-existent key, it returns null rather than throw an exception. Below are two ways to set values.
NameValueCollection list = new NameValueCollection();
list["key1"] = "value1";
NameValueCollection list2 = new NameValueCollection()
{
{ "key1", "value1" },
{ "key2", "value2" }
};