Could you use a custom connection file ? Then pass it into MSTSC E.G:
mstsc customfile.RDP
Here's what a RDP file looks like, I saved credentials, note the FULL ADDRESS field and the USERNAME field.
screen mode id:i:2
use multimon:i:0
desktopwidth:i:1680
desktopheight:i:1050
session bpp:i:32
winposstr:s:0,3,0,0,800,600
compression:i:1
keyboardhook:i:2
audiocapturemode:i:0
videoplaybackmode:i:1
connection type:i:2
displayconnectionbar:i:1
disable wallpaper:i:1
allow font smoothing:i:0
allow desktop composition:i:0
disable full window drag:i:1
disable menu anims:i:1
disable themes:i:0
disable cursor setting:i:0
bitmapcachepersistenable:i:1
full address:s:###.###.###.###:####
audiomode:i:0
redirectprinters:i:1
redirectcomports:i:0
redirectsmartcards:i:1
redirectclipboard:i:1
redirectposdevices:i:0
redirectdirectx:i:1
autoreconnection enabled:i:1
authentication level:i:2
prompt for credentials:i:0
negotiate security layer:i:1
remoteapplicationmode:i:0
alternate shell:s:
shell working directory:s:
gatewayhostname:s:
gatewayusagemethod:i:4
gatewaycredentialssource:i:4
gatewayprofileusagemethod:i:0
promptcredentialonce:i:1
use redirection server name:i:0
username:s:<USERNAME>
pass that to the mstsc.exe call. I'll try and see where the password is stored.
I wouldn't call this super secure either. I think the password is stored encrypted, it'll be a few minutes until I figure out how.
What are you trying to accomplish exactly? MSTSC doesn't return values based on authentication. So, I'm not sure what you plan on capturing.