From my research I believe this is possible with Microsoft's 'Multigeo', but I believe this needs 5000 users, not 100. I do remember there are other ways around this, perhaps multi-tenants but then I'm unsure whether two tenants can be completely synchronized with the same domain name.
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1Why do you need this? – Jim B May 25 '18 at 02:07
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Company has two offices based in separate countries - due to company security/data policies they would like user mailboxes stored in the country where the staff member is located. – Adam Ash May 25 '18 at 03:37
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Yes, it's possible by Multi-Geo Capabilities in Exchange Online. We need to configure PreferredDataLocation attribute in Azure AD, for example:
Set-MsolUser -UserPrincipalName <UserPrincipalName> -PreferredDataLocation <GeoCode>
And, Yes, 5000 is the minimum limitation in one Office 365 tenant for this feature.

Jianfei Wang
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