Basically you could just ping or try using NMAP
tool in ping scan mode:
nmap -sP -Pn 192.168.1.*
192.168.1.* is your network
It will detect if IP addresses are assigned and shows more details for assigned ones.
To clarify the situation, you might want to read more about Network Classes and Sub-networks:
In the IPv4 address space certain address blocks are specially
allocated or reserved for special uses such as loopback interfaces,
private networks (RFC 1918),1 and state-less autoconfiguration
(Zeroconf, RFC 3927)[2] of interfaces. Such addresses may be used
without registration or allocation from Regional Internet Registries
(RIRs). However, these address ranges must not be routed into the
public Internet infrastructure.
The netmask is a bitmask that can be used to separate the bits of the
network identifier from the bits of the host identifier. It is often
written in the same notation used to denote IP addresses.
Not all sizes of prefix announcement may be routable on the public
Internet.
The blocks numerically at the start and end of classes A, B and C were
originally reserved for special addressing or future features, i.e.,
0.0.0.0/8 and 127.0.0.0/8 are reserved in former class A; 128.0.0.0/16 and 191.255.0.0/16 were reserved in former class B but are now
available for assignment; 192.0.0.0/24 and 223.255.255.0/24 are
reserved in former class C.
While the 127.0.0.0/8 network is a Class A network, it is designated
for loopback and cannot be assigned to a network.