If I understand the question right, you want to list who is a local administrator on each machine in your domain?
You'll have to connect to each machine and list the local Administrators group. As far as I know, this information isn't kept in Active Directory or anything. There's several ways to go about this, but one way to do this is to use the free tool psexec to dump the group membership on each PC.
First you'll have to generate a list of all the Windows machines you'd like to get this info for. Save it to a plaintext file, with the hostnames or IPs each on their own line.
From a command prompt, run this command:
psexec.exe @hosts.txt -u user -p password net localgroup
"Administrators" > outputfile.txt
(Where user and password are a domain admin account).
This will take quite a bit of time, depending on the amount of hosts you're scanning, but you should have a list of the groups/accounts that have local admin access.