I've been contemplating attempting this as I have a 64GB SDD to play with for a short while (maybe longer, we'll see...). However, I'd expect that the OPs machine has a Z68 chipset and is using Intel's Smart Response Technology so that the SDD is used as an active, adaptive, cache.
One issue, however, that using a standard MLC SSD may have in an SRT config is that I don't believe TRIM can function on the cache SSD, so write speeds will eventually become abysmal and you may need to wipe the drive PROPERLY (no quick format, here...) to regain those write speeds...
Intel SSDs may show less of a problem, however, as they do maintenance across writes, however their performance isn't as drastic when compared to a nice Crucial M4 - but the M4/C300 relies on TRIM support to prevent slow-downs...
That said, I'd think that RAID 0 with an SSD and a HDD would result in an averaging of performance between the two drives.
When a read in RAID 0 occurs, the controller organizes the reads in stripes across the drives, so the first 64KB comes from the SSD, and the second comes from the HDD. If you are making a small read, you will be playing Russian roulette as to which drive will contain the data (odd stripes on SSD, even on HDD, or the modulus of the drive count, more accurately[without going overboard....]). A large read will see an average of the seek times and read performances.
It would be somewhat schizophrenic... and the SSD would spend 50% of its life or more waiting on the HDD to do something...
My solution would be to use the SSD as boot and core applications, and then to install large applications to a standard hard drive (this coming from a guy who is running a 2x2 RAID 10 boot volume, 3x0 RAID 0 for additional, fast, storage, and a >2TB server for backups ;-) ). If you have an odd application that requires itself to be installed on "C" then you can merely create a "junction" ( mklink /j [link] [path] ) so that the data is redirected to the storage location of your choice, and the application is none the wise ;-) Also a great way to move existing installations in the future without messing with re-installs...
--The loon