Those are both AWS EC2 IP addresses: ec2-52-2-212-237.compute-1.amazonaws.com
and ec2-44-207-101-129.compute-1.amazonaws.com
, respectively (per https://whois.domaintools.com).
CloudFront caches your server's content for 24 hours by default. After that time, the next request for each resource will reach your server, and whatever your server returns will be cached for the next 24 hours. That means, assuming there's a fairly constant stream of requests from the internet to your site, you'll see a spike once per day, and those requests will appear to your server to have come from CloudFront or the load balancer (depending on what type of load balancer, I believe).