They will break apart, but very slowly - it may take two years.
However, instead of disposing them, you can do some useful things with them.
If you or your friend keep frog tanks, you can use magnolia seed pods there:
http://www.dendroboard.com/forum/general-discussion/84047-who-uses-magnolia-seed-pods.html#/topics/84047?page=1
I now have them in many tanks and they seem to work out well. I also put them in my water features with my groups of Anthonyi and the tadpoles seem to like to hang out around them. Several have been directly in the water for several months now and are still holding up very well.
Also, if you collect and keep them in one place, you get free microfauna hotel.
Or, you can use them as very useful components of insect hotels like this one:

(source: elmundo.es)