Can you cook some foods just placing them in a metal frame above hot oil? In the same way as steaming vegetables, but with oil. Is that a thing?
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25Given how badly you can get burned by steam, I'd be really, really afraid of hot oil vapor – Joe Apr 10 '18 at 18:03
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22@Joe Unlike water vapour (steam) oil vapour would most likely explode before it gets a chance to burn you. Google fuel-air bombs – slebetman Apr 10 '18 at 20:22
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@Joe: Calimo already pointed out what makes steaming so effective (2230 J/g heat of condensation), that's also what makes steam dangerous. Oil is safer in this respect - until it catches fire, of course. – MSalters Apr 11 '18 at 00:16
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9If you like your kitchen ceiling to be a nice yellowy brown colour. – RedSonja Apr 11 '18 at 10:53
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1Are you already cooking something else in the oil, and just trying to reuse the heat? – Aaron Hall Apr 11 '18 at 12:51
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19The boiling point of oil is higher than the catch on fire in a dramatic way temperature of oil – wedstrom Apr 11 '18 at 16:37
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3I can't help but think of one of my medievalist friend's experiments in making boiled linseed oil. The resulting fireball is quite famous around these parts. (Thankfully, nobody got hurt.) – Marti Apr 12 '18 at 00:30
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2With "[catch on fire in a dramatic way temperature](https://en.wikipedia.org/wiki/Autoignition_temperature)" being the correct scientific term to use there. – aroth Apr 12 '18 at 01:59
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There is simply nothing else to say about this than shout DO NOT TRY THIS UNDER ANY CIRCUMSTANCE. – Apr 13 '18 at 07:51
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Another probably dangerous but at least feasible idea would be to do the same thing with alcohol, which would cook the food at a lower temperature than traditional steaming (since its boiling point is lower) and probably make the food quite boozy... the risk also being that the alcohol could catch on fire. One could also play with the cooking temperature by adding salt to the water to raise its boiling point. – A.N. Apr 14 '18 at 12:09
8 Answers
That really wouldn't work.
With steaming the water is heated to boiling which creates steam. Since the food is colder, the steam condenses on the food which transfers heat to the food.
With hot oil there is no boiling and vapor of the oil. So in an enclosed container it would be more akin to baking, the hot oil heating the air, than steaming. (There would be some oil in the vapor above hot oil, but not enough to transfer much heat.)
(1) Another factor here is pointed out by user "Lorel C" in another answer. Cooking oils tend to decompose and smoke before reaching their boiling point. If you could get oil to boil without smoking, then "steaming" in the boiling oil vapor would be very close to frying in oil, but at a temperature much above what is normally used.
(2) Also as user "yo" points out in a comment below, the bubbling that you see when frying something isn't the oil boiling. Rather it is the water coming from the food that is vaporizing.
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4I think the suggestion is the oil is so unbelievably hot that it vapourises. I can't see any good outcome from this (in particular I don't think oil vapourises before it denatures, i.e. reaches its smoke point) – Richard Tingle Apr 11 '18 at 18:17
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1@RichardTingle - The OP specified "hot oil" not "boiling oil." Being a southerner in the US we like everything fried. But I've never fried with *boiling oil*. – MaxW Apr 11 '18 at 19:21
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8"In the same way as steaming vegetables" implies vapour. I'm not arguing that this is a good idea but you could try to do it (and either produce vast quatities of smoke or burn your house down) – Richard Tingle Apr 11 '18 at 19:31
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7@MaxW It may be important (to someone) to note that when people see "oil boiling", it's actually water content of whatever you fry that's boiling, and not literally oil boiling. – yo' Apr 12 '18 at 09:44
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... and the water vapour created by whatever you are frying is what carries the small oil droplets around the kitchen until the water either condensates or evaporates and leaves the oil droplets falling down on the top of your cabinet =) – Earthliŋ Apr 13 '18 at 12:13
I have never heard of anyone "steaming" vegetables using oil instead of water. Placing them in a metal frame above hot oil would not be as effective as cooking them surrounded by steam (from water). The hot oil would need to be boiling.
According to
https://www.researchgate.net/post/What_is_the_boiling_temperature_of_cooking_oil_palm_oil_Any_reference
"The exact boiling temperature depends on how pure the oil is. The boiling point for palm cooking oil is estimated in about 300 C (or 572 F)." That kind of temperature seems like overkill for vegetables. Also the smoke point for cooking oils is lower than their boiling point, so it would be messy, unpleasant (with all that smoke in the kitchen), and, judging from the comments contributed by others, it would be extremely, crazy-dangerous as well.

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23The smoke point being lower than the boiling is the important part. The smoke would given an awful taste to the food. // There must be some other liquid that you could use for steaming. Ethanol comes to mind, but vaporous ethanol is a significant fire hazard. I certainly wouldn't try it in a home kitchen. – MaxW Apr 10 '18 at 17:22
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@MaxW would ethanol even work? Would it have the opposite problem from oil - it would evaporate well before it reached a temperature that would cook any vegetables? – stannius Apr 10 '18 at 18:29
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15Steaming works not because water vapor is hot, but because it has a very large latent heat for the water-vapor phase transition (around 2,230 J/g if I can trust the Internet), which is released when the water condensates. I can't find the equivalent for oil, but I wouldn't be surprised if it is way lower than that. – Calimo Apr 10 '18 at 19:00
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14If you can ever produce a significant amount of oil vapour it is actually an explosive. Same with any other kind of situation where fuel gets mixed with lots of air. Sawdust and flour explosions are known phenomena. Fuel-air explosions are in fact used by the military to create some of the most powerful non-nuclear bombs in the world – slebetman Apr 10 '18 at 20:20
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@immibis, wow, I guess I didn't know the half of it! ... I better fix that, eh? – Lorel C. Apr 11 '18 at 04:06
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@stannius - ethanol boils at 78 °C (173 °F). Not sure if that would be enough to cook any vegetable or not. But again, vaporous ethanol is a significant fire and explosion risk so i wouldn't try it. – MaxW Apr 11 '18 at 05:50
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1@Calimo Exactly. Water has a very high heat of vaporization compared to most other compounds. There's no other common liquid that is both safe to use with food and can release as much energy on condensation as water. – barbecue Apr 11 '18 at 15:34
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@MaxW steaming with ethanol in a pressure cooker so it doesn't escape. like lower temperature steaming. I'm a tiny bit curious if that would work. – userLTK Apr 12 '18 at 18:58
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1@userLTK - But some vapor (water or ethanol) does escape from a pressure cooker. Such ethanol vapor in a kitchen is a significant fire/explosion hazard. Somewhat idiotically I mentioned ethanol because as a chemist it was the only other liquid that I could think of that would safe for human consumption. Ethanol would boil and not smoke like any of the various cooking oils that are used in a kitchen. The flash point of pure ethanol is less than the average room temperature. **Again trying to use ethanol for steaming in a home kitchen is not safe.** – MaxW Apr 12 '18 at 19:14
As already said, this wouldn't work at all with any normal fat. I'd further emphasize that it's really quite dangerous: fat can spontaneously ignite when heated substantially over the smoke point. And if you drop anything water-containing (like one of the pieces of vegetable) into hot fat, the water will boil with a sudden violent expansion. When the fat is already aflame, this can result in a literal fiery explosion. (The reason why fat fires must never be extinguished with water.)
That said, if you use a pure, saturated, short-chain fatty acid like lauric acid, you could get this to work because it chemically withstands the 300°C needed to get it boiling. These vapours would then indeed “steam” your vegetables. It would not actually get the vegatables to 300°C because the water content has a high heat capacity; a lot of fatty vapour would need to condense on the surface to even reach 100°C. I reckon the result would actually be more like soaking the vegs in a cold deep-fryer, which is then heated up slowly. If you'd do it long enough, the water would eventually evaporate, after which the temperatures would go up much higher – the food would eventually be dry-singed.
Pure lauric acid isn't toxic, but it would probably impose a soapy/waxy taste on the food.

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Also... what would be if you started off in a lowered pressure environment, letting it saturate with oil vapor until atmospheric pressure is reached.... is thermal conductivity of an oil vapor no better than air? – rackandboneman Apr 11 '18 at 20:53
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1@rackandboneman: Steaming doesn't work by thermal conductivity. It works by convection, and very efficiently so when the heat transferred is released by condensation. – MSalters Apr 13 '18 at 14:13
You can, but the oil will smoke before it boils and the oil will require a lot of heat to actually come to a boil.
It's possible, but really really inefficient.
https://www.oliveoilsource.com/asktheexpert/what-boiling-point-olive-oil
According to that article it would also be dangerous.
Most importantly, from an objective standpoint, you would heat the oil up too much and ruin the flavor. Your vegetables would not taste good if you did this.
I'm assuming that you're just looking for cool ways to cook stuff at this point. You should try roasting things with sand or salt. The youtube channel cookingshooking has a lot of videos where the host cooks things like pizza without an oven using salt in a pressure cooker. This would cook your vegtables well in a unique way.
If you want your vegtables to be coated in a little bit of oil then you can just sprinkle oil on them or toss them in a bowl with oil to coat them.
Even if you could steam oil without it combusting, it wouldn't transfer nearly as much energy as steam does.
Water has an obscenely high specific heat, just around 4. Here
Oil has a specific heat around 2, depending on the type of oil. Here, Table 6
it takes approximately one crapload of energy to turn water into steam. That energy is still in the steam as it rises, and is transferred to anything that it touches. That is why steam has a such a high scald hazard despite being 'only' 100 C. Oil, with its lower specific heat, would not transfer energy as efficiently.
Yes, you can "steam" using oil. When you steam with water, the hot water condenses on the cold food and transfers the heat. With oil, you mist the food with oil and then heat the air. The oil transfers the heat to the food. It's called "air frying."

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Unless that airfrier keeps a constant oil mist going? But I would guess it doesn't, hot oil mist sounds like a proper safety hazard... – rackandboneman Apr 11 '18 at 20:49
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2Hello, and welcome to Stack Exchange. The original question was about heating food **over** oil (as opposed to over steaming water). – Daniel Griscom Apr 11 '18 at 21:27
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You can in fact. It would not be practical and traditional streaming methods are more precise and less dangerous however, when frying particularly moist foods (like fries) especially in large quantities, steam is produced. This steam isn't enhanced with flavor and there really isn't any benefit to doing it this way. Which is probably why it isn't.

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Possible to do this safely in an atmosphere without Oxygen, but it would still taste bad.
As other answers mention, the smoke point is lower than the boiling point, so food cooked in oil vapor would taste horrible. By removing the Oxygen, you won't prevent smoking. But you will reduce the fire hazard.
One method to do this, and prevent other reactions between the hot oil and the air, would be to remove all the normal air from a room and replace it with a much less reactive Helium.
For obvious reasons, this is not a frequently used cooking method. When someone does this, it will make a great youtube video. Perhaps the food will taste good too.

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2“Smoking is a chemical reaction between Oxygen and hot oil” – that's not true. Smoking is simply the decomposition of fat molecules through thermal excitation. The _products_ of that decomposition can then react with oxygen (that's what can kick off the spontaneous ignition), but removing the oxygen does not prevent the fat from smoking, it just makes it less catastrophic. — Using an inert gas is not a bad idea, also for other purposes, but [argon is a much better choice than helium](https://en.wikipedia.org/wiki/Argon#Preservative). – leftaroundabout Apr 12 '18 at 15:25
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@leftaroundabout: ah, yes, I've heard about cooking things with argon-oil. Badum and/or tish. – Steve Jessop Apr 13 '18 at 19:42